If you've tried to move a SkyDrive older but you've noticed that the "Unlink SkyDrive" button is greyed out, and also seen the message that "This option is unavailable because you're signed in on this PC with a Microsoft account. If you want to use a different account with SkyDrive, sign in on this PC with a different Microsoft account or add an account on this PC with the email address you want to use." (which is a very verbose but still not relevant message to your situation) you'll want to follow the steps in this video. I also cover linked accounts, Microsoft accounts, local accounts, and domain connected accounts in this episode. So for a short episode, this one is pretty packed.